| dc.contributor.author | Akkurt, Nihat | |
| dc.contributor.author | Al-Jumaili, Mohammed Hadi Ali | |
| dc.contributor.author | Ocak, Hale | |
| dc.contributor.author | Cakar, Fatih | |
| dc.contributor.author | Torun, Lokman | |
| dc.date.accessioned | 2021-12-12T17:02:33Z | |
| dc.date.available | 2021-12-12T17:02:33Z | |
| dc.date.issued | 2020 | |
| dc.identifier.issn | 1300-0527 | |
| dc.identifier.uri | https://doi.org/10.3906/kim-1912-51 | |
| dc.identifier.uri | https://hdl.handle.net/20.500.11857/3487 | |
| dc.description.abstract | In this study, we reported the synthesis of a new tribranched macromolecule liquid crystal with triazine in the centre. The central triazine core is bonded via sequences of Sonigashira coupling to 3 triazine unites through acetylenic bridges. The triazines at the periphery are substituted with 2 chiral citronellyloxy side groups. The salt of the resulting star-shaped macromolecule, which was oily at room temperature, with 4-dodecyloxybenzoic acid at 1:1 ratio exhibited a Smectic C (SmC) mesophase. The liquid crystalline properties of organic salt were investigated using DSC (differential scanning calorimetry) and POM (polarizing optical microscopy). | en_US |
| dc.description.sponsorship | TUBITAKTurkiye Bilimsel ve Teknolojik Arastirma Kurumu (TUBITAK) [114Z722]; Yildiz Technical UniversityYildiz Technical University [201501-01-DOP04] | en_US |
| dc.description.sponsorship | Authors thank to Professor Belkis Bilgin Eran for valuable discussions on POM studies. This work was supported by TUBITAK with the project no 114Z722. We also thank Yildiz Technical University with the project no 201501-01-DOP04. | en_US |
| dc.language.iso | eng | en_US |
| dc.publisher | Scientific Technical Research Council Turkey-Tubitak | en_US |
| dc.relation.ispartof | Turkish Journal of Chemistry | en_US |
| dc.identifier.doi | 10.3906/kim-1912-51 | |
| dc.rights | info:eu-repo/semantics/openAccess | en_US |
| dc.subject | Triazine | en_US |
| dc.subject | ionic liquid crystals | en_US |
| dc.subject | hydrogen bonding | en_US |
| dc.subject | star-shaped triazine | en_US |
| dc.subject | Sonogashira coupling | en_US |
| dc.title | Synthesis and liquid crystalline properties of new triazine-based pi-conjugated macromolecules with chiral side groups | en_US |
| dc.type | article | |
| dc.authorid | Cakar, fatih/0000-0001-6192-1370 | |
| dc.authorid | Akkurt, Nihat/0000-0002-0781-7983 | |
| dc.authorid | Aljumaili, Mohammed/0000-0002-4666-0886 | |
| dc.department | Fakülteler, Fen-Edebiyat Fakültesi, Kimya Bölümü | |
| dc.identifier.volume | 44 | en_US |
| dc.identifier.startpage | 726 | en_US |
| dc.identifier.issue | 3 | en_US |
| dc.identifier.endpage | + | en_US |
| dc.relation.publicationcategory | Makale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanı | en_US |
| dc.authorscopusid | 57211408821 | |
| dc.authorscopusid | 57211409139 | |
| dc.authorscopusid | 16176119400 | |
| dc.authorscopusid | 8701613500 | |
| dc.authorscopusid | 6508024090 | |
| dc.identifier.wos | WOS:000538115400014 | en_US |
| dc.identifier.scopus | 2-s2.0-85090252772 | en_US |
| dc.identifier.pmid | PubMed: 33488189 | en_US |
| dc.authorwosid | Cakar, fatih/ABF-9696-2020 | |
